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in: PubMed | Google Scholar Authorship note: LK, RFM, and KA contributed equally to this work

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For [s 4 Urd+H] + , the lowest energy hydroxyl-sulfhydryl tautomer adopting a syn conformation, TE S4 , lies only 56 kJ/mol higher in free energy than TA S4 and displays an O2HO5 hydrogen bond